|
Boy Scout Troop 446 |
Saline Michigan |
|
Pulp and Paper Merit Badge Information |
Text from 1999 Printing of the 1993 Edition |
|
For more information check with the troop Library |
|
The paper industry is complex and ever expanding. Paper consumption increases with the standard of living and has steadily increased since paper was invented nearly two thousand years ago. The paper industry is effectively solving its pollution problems and is not about to run out of raw materials as many people believe.
It is hoped that this pamphlet will lead to a better understanding of this great industry and perhaps guide some of the youths of our land into rewarding careers.
In other places where papyrus was not available, split sheepskins were used (about 1500 BC). Skins were split, dried, scraped, chalked, and pumiced. Both papyrus and split skins were used in the Roman Empire.
Paper was invented in China about A.D. 105. It was made from fermented and beaten mulberry bark fibers. These fibers were suspended in water and scooped out with a screen made of bamboo splinters tied with horsehair. The papermaking process remained a Chinese secret until A.D. 704 when Arab armies captured a city named Samarkand in western China. Several Chinese papermakers were abducted to Baghdad and put to work making paper. Other raw materials were developed. In A.D. 794 the Chinese workers of Baghdad made paper from linen rags.
Papermaking spread rapidly throughout the Muslim world. Even the art of block printing had, by then, been invented in China and had followed papermaking. However, by that time the Roman Empire had fallen, and the Muslims held Asia Minor and Africa while the Christians held Europe. During the bitter wars (Crusades and Muslim invasions) Europe was cut off from Egyptian papyrus and from the growing paper technology. As late as A.D. 1450, Johannes Gutenberg, the inventor of the printing press, used three hundred sheepskins to print a single Bible.
Paper was first brought to Europe by the Moors that invaded Spain. About A.D. 1150 a paper mill was built in Spain. From there papermaking slowly spread through Europe. England did not produce paper until 1494 (two years after the discovery of America). The English recognized the importance of paper and rapidly took the lead in its manufacture. Paper was soon used for designing English ships. Prior to this, shipyards built oceangoing vessels in a haphazard manner without plans. Thus, paper again influenced world history by contributing to Englandıs superiority on the waves.
English settlements in America developed rapidly, and they soon needed paper in ever-increasing amounts. In 1690 Rittenhouse established the first American paper mill in Philadelphia. Using linen rags as a raw material, this plant made one hundred pounds of paper per day. The process used in this mill was still very crude. Paper pulp was prepared by letting wet rags ferment for six to seven weeks. Rotting loosened the fibers. Unfortunately, it also gave a coffee-brown color. This stock was then cooked in limewater, broken up by stamping, placed in bags, and washed in the stream. One-third of the original stock had rotted and was washed away. The remaining washed product was bleached in the sun, suspended in water, then dipped from the water with a wooden frame that had a screen on the bottom. The frame was shaken as the water drained, leaving a wet mat. These mats were removed from the screens with felt blankets, stacked between the blankets, pressed to remove water, and finally hung in a loft to dry. Paper was made in this manner until the middle of the nineteenth century. Since this process was slow and rags were hard to get, paper was always in short supply
In 1799 the Fourdrinier paper machine was invented. A pulp suspension was spread on a moving wire screen, and, after the water drained off, a continuous wet sheet was removed. The modern paper machines on which most of our paper is made today are improved Fourdrinier machines.
In 1809 the cylinder machine was invented. On this machine sheets were formed on rolls. Several sheets were pressed together when wet, and a board-like laminate was formed. The resulting layers can be found in cardboard and book matches.
Drying the wet sheets of paper and board continued to be a serious problem. In 1826 steam-heated cylinders were first used for drying the paper. Unfortunately, this equipment had to be cranked by hand or water power since motors had not yet been invented.
As the process improved, papermakers were limited mainly by the scarcity of rags. During the Civil War some desperate paper mill executives even imported mummies from Egypt to make pulp from the wrappings.
People constantly looked for other sources of fiber including straw, rope, and wood. Wood provided a good source if the individual fibers could be separated. Mechanical and chemical pulping processes were slowly developed during the last century. These processes are described later in this book. Their development overcame the rag shortage and made the modern paper industry possible.
If this vision for the future surprises you, remember that we live in a time of constant progress and change, and every product on the market today is subject to this change.
The answer to this question is no! First of all, wood is a renewable resource. Unlike petroleum and ores, wood can be made by planting trees. With good forest management the amount of wood grown and harvested in the United States can be tripled without increasing the forest lands. These forests could still be used for wildlife, recreation, and watershed.
Secondly, huge tropical forests have not been used because there are too many different types of trees that cannot be pulped or can not be pulped together by the same process. However, if more research was directed toward the pulping of these species, productivity could be increased and diversity maintained in the tropical forests. A great source of pulpwood would result because in the tropics trees grow even more quickly than they do in the southern United States.
Thirdly, there are many other renewable fiber sources. Bagasse, the waste of the sugar industry, yields good papermaking fibers. Bamboo and other grasses are used in some countries. Even seaweeds and fungi are being considered in research projects.
Fourthly, great progress is being made in recycling wastepaper. We can never reach the point where all paper products are made from recycled waste. However, we do not need to. We only need to make enough paper from recycled waste so that the difference between the demand for paper and the supply from recycling can come from trees and other sources. Indeed, paper cannot be recycled again and again,because the paper fibers are shortened during processing.
After several reuses the fibers get too short for papermaking and must be discarded either in landfills or burned for energy recovery.
The groundwood process has many advantages. The wood is not cooked. This means that no expensive cooking chemicals, cooling vessels, or heat are needed. The lignin is not removed. Lignin is a chemical substance that forms with cellulose to bond the fibers together in the tree. In the groundwood process all of the wood is used to make paper. This gives us the most paper from each tree.
The disadvantage of this process is that due to the lignin, the paper discolors, especially in sunlight. This pulp is used for making newspaper, certain tissues like toilet paper, some wrapping paper, and colored wallpaper. Paper made from groundwood pulp is very weak but makes paper with good printing properties.
Thermomechanical pulping process (TMP). Mechanical pulping produces pulp by processing moist wet chips in a refiner. The thermomechanical process involves presteaming chips at high temperatures and refining them in a disk refiner. The disk refiners have two plates with grooves on the faces of the plates. These plates can be up to six feet in diameter. During the refining process the plates turn rapidly in opposite directions while the wet chips and water pass between them. The chips are torn into a mass of fibers. TMP can be produced under pressure or at atmospheric pressure in the refiner. This pulp makes a stronger paper than paper made from ground wood pulp. Its uses are similar to those of ground wood pulp.
Chemithermomechanical pulping process (CTMP). This process is similar to the TMP process except chemicals are used in conjunction with refining. Chemicals such as sodium sulfite and chlorine dioxide are used to oxidize certain materials in the wood chips. This process produces a stronger pulp than TMP from which stronger paper can be made. The application of chemicals is normally done prior to the preheating and steaming of the chips, but the chemicals can also be added during or after refining. In addition to superior strength, the absorption characteristics of the pulp are much improved over those of TMP. This superior pulp strength and absorbency of CTMP makes it useful in products that TMP cannot be used for. For example, CTMPıs use in tissue paper is made possible because the chemicals used in the CTMP process remove resins that are responsible for reduced water absorbency in TMP. CTMP can also be used alone in newsprint and telephone directories.
The most important chemical process is the sulfate or kraft process. This process yields some of the strongest papers made. (Kraft is the Swedish word for strength.) Almost any species of wood can be used. The debarked logs are chipped into half-inch chips that are cooked in digesters at high temperature and pressure in a solution of sodium hydroxide and sodium sulfide for about three hours. The chemicals remove the lignin, which is the binding material between wood fibers. After cooking, the pulp is blown into the blow tank. A brown, hard-to-bleach but very strong pulp is produced. It is used for making paper for strong bags, wrappings, tape, paperboard cartons, milk bottles, oil cans, etc. The liquor is recovered, concentrated by evaporating water, and burned. The heat from burning is used to make steam and electric power for the mill.
The chemicals in the liquor are recovered from the furnace slag for reuse. The liquor that is burned contains lignin, carbohydrates, and byproducts such as alcohols, organic acids, sulfides, and mercaptans. The latter two are very foul smelling and belong to the same family of chemicals as "rotten egg odor" and "essence of skunk." Much research has been done and great progress has been made in eliminating this odor.
Another common process is the sulfite process, which uses mainly spruce and some hemlock and fir. The liquor for cooking the chips is made by burning sulfur to sulfur dioxide and absorbing the sulfur dioxide gas in water in a tower filled with limestone. The resulting liquor is a solution of calcium bisulfite and some magnesium bisuL fite. The chips are cooked for ten to eleven hours at 220° to 310°F. The resulting pulp is screened, thickened, and bleached.
Sulfite pulp is used for bond, writing, high-grade book, and other fine paper. Formerly the liquor could not be reused and was dumped into the nearest stream. Research has shown that it can be used for the manufacture of some byproducts such as vanillin, alcohol by fermentation, tanning materials, road binders, cement additives, plastics, etc. However, recovery of chemicals from this liquor is still a problem. As a result, not many mills use this process.
The oldest pulping process-rag pulping-is still used. New rags-scraps from the textile industry-are preferred, but old rags from waste are also used. Old rags must be sorted; synthetics and silk must be removed; and zippers, buckles, belts, and the contents of pockets must be discarded. Sometimes the waste must be sorted by color so that a white product may be obtained.
The rags are cut into small squares; dusted in a mechanical dust remover; cooked in lime, caustic soda, or lime and soda ash for ten to twelve hours at 250° F; then washed, bleached, and rewashed. The resulting pulp is used for the manufacture of fine writing papers, bank notes, security papers, documents, lightweight papers (such as cigarette, carbon, and tracing paper; vellum; and blueprint papers), and for plastic laminates (such as football helmets, shin guards, shoulder pads, plastic gears, and machine components, etc.). Other pulping processes have been developed to use fibrous materials that would otherwise be wasted or to use special fibers in countries that do not grow pulpwood. These include sugar cane bagasse, straws, bamboo, and other materials of minor importance.
Another source of pulp is wastepaper, which presently furnishes about one-quarter of all pulp fiber used in the United States. Recycled boxboard mills defiber the wastepaper mechanically to make it into paperboard without deinking. In some mills old papers are sorted, shredded, dusted, and cooked in caustic liquor to break the vehicle in the ink so that the ink can be removed. An ever increasing quantity of wastepaper is re-pulped and de-inked to produce pulp for further paper manufacture. This process has a great future. Getting rid of wastepaper is now a problem. Increased demand for paper products results in a growing need for papermaking fibers. What is more natural than to reuse the waste?
However, the recycle process has several serious disadvantages. Much of the raw material is mixed with undesirable materials of all kinds including plastics, glue, foil, wax, metals (staples), and all kinds of dirt and garbage. These must be removed on a large scale without expensive hand sorting. Furthermore, if printing and writing papers are to be made, the inks must be removed. This can be done, but then the ink must be removed from the wash water. Recycling can cause pollution.
Recycling paper is a big job for the paper research groups of today. Much effort is put into cleaning and deinking pulp and into cleaning the wash water. The process must be economical when compared with processes using new fiber from trees. If collecting, sorting, cleaning, deinking, etc., cost more than wood pulping, the company will not be able to compete. Recycled fibers can, of course, be used for making boxes without deinking. Since many boxes are used for food packaging, care must be taken that no toxic materials are recycled. Wastepaper cannot be hand sorted economically, so the use of toxic materials in products like office papers must be restricted.
After the pulp has been produced from wood, waste, paper, rags, bagasse (sugar industry waste), bamboo, straw, or other fibrous materials, it is cleaned by screening a suspension of 1 part pulp to 200 parts water.
Water-soluble impurities are removed by several countercurrent washing stages. The last wash is made in fresh water, with the used wash water passing to the next to last washer and so on. In this way the pulps get washed in clean water while the impurities are concentrated in as little water as possible to make waste treatment or chemical recovery easier.
In each washing step, the pulp is separated from the water by large, rotating circular screens with fine mesh.
To produce white paper, the pulp must be bleached. The bleaching agents are the same as those used for bleaching cloth. They are usually calcium or sodium hypochlorite (household bleach), chlorine dioxide, sodium peroxide, hydrogen peroxide, oxygen, or ozone. These materials either remove the color-causing compounds or make them colorless.
Bleaching is often performed in a series of steps using different chemicals in each state. The operations are carried out in tall vessels called bleaching towers. The bleaching is a continuous operation, with the pulp moving from stage to stage. Each stage has its own chemical addition and washing station.
Beaters are also used to blend pulp; to add filler (such as clay), which occupies space between the fibers; to improve the brightness, appearance, and ink reception; to add size (such as rosins and wax emulsions), which makes paper more water resistant; to add coloring agents; and to add alum, which sets the size and dye and prevents their loss during the paper-forming step. Polymers are often added to improve water drainage and the consolidation and bonding of fibers to improve the properties of the final papers. Sometimes wet-strength resins are added. This makes the paper stronger when dry, and it also keeps one-fourth to one-third of its strength when wet.
The resulting pulp is once more screened and in some cases passed through a centrifugal cleaner to remove heavy particles of dirt that have not as yet been removed. It is then diluted to 0.5 percent consistency (0.5 percent fiber, 99.5 percent water) and pumped to a paper machine. Pulp is dried by machine for shipment to a distant paper mill. Water Pressed Out The Fourdrinier papermaking machine is still the most common. It consists mainly of a continuous fine screen, called a wire, on which the pulp suspension is spread. The wire moves at a speed of 200 feet per minute for some specialty paper to 4,000 feet per minute for tissue, and may range from widths of 4 to almost 30 feet.
By the time the paper nears the end of the wire, most of the water has been drained from the mat. The wire then passes over a series of vacuum suction boxes that suck more water from the wet mat through the wire. The wet paper leaves the Fourdrinier wire at a consistency of about 20 percent (20 percent fiber and additives, 80 percent water).
The dried paper is passed through a series of heavy, smooth cast-iron rolls called calendar stacks, which further smooth the surface. Wet end of a paper machine, above. It is then wound into a large roll. The paper is later rewound and cut to the desired roll sizes for sale or for further processing. Some papers, such as tissue papers, are dried on a Yankee dryer, a large, rapidly turning drum heated with very hot high-pressure steam. Heated air is blown into the machine to speed drying. Large rolls are and cut into smaller rolls (such as toilet tissue rolls).
A good grade of pulp is frequently used on the last cylinders to give the outside of the board a good appearance. The second sheet is often made of a slightly poorer grade, while the inner layers are normally reclaimed paper of poor grade. A common example is found in book matches. A book match can be separated into several thin layers of paper. The outer sheet is white or dyed; the inner sheets are dirty gray.
Needless to say, paper machines are changing rapidly. The Fourdrinier machine is being replaced by a number of new models. Some of these are horizontal like the Fourdrinier with wire screens on the top as well as the bottom of the sheet, while others are vertical. In either case water is removed from both sides of the sheet. This helps prevent one-sidedness. Both sides of the sheet are formed alike. This is not true when only the underside of the sheet is in contact with the forming wire since the water leaves through that side, taking some small particles with it.
The cylinder machine is also being replaced by new machines that lay down several sheets on top of each other and remove water from both sides after each layer is placed. In addition there are now several types of vatless cylinder machines.
In general, machines are getting wider and faster. Paper speeds as fast as a mile per minute have been reached.
The dryer section is also changing. Some machines have both a multiroll section and a high-temperature Yankee dryer. Some machines have infrared heat lamps in addition to the steam-heated rolls.
As the machines get larger and faster, the air system for removing the water vapor also becomes more complicated. As mentioned before, a large mill making 1,000 tons of paper per day takes in about 50 million cubic feet of air per hour, heats it so it can pick up the water vapor, and blows it out into the surroundings. This is equal to a IOO mile-per-hour hurricane through a duct 10 feet high by 10 feet wide (100 square feet).
Indeed, as the paper machines get larger and faster and the mills get larger, every part of the mill must also get larger. This means that even small improvements that save very little money become important. If an employee in a 1,000 ton per day mill finds a way to save a tenth of a cent per pound of paper made, he saves his company about $700,000 per year. This makes competition for improvements very keen. The paper industry is operating on a low profit margin. A cost difference of a fraction of a cent per pound can make the difference between staying in business or shutting down. This makes paper engineers important. If they fail, their company fails with them.
Several methods are used for applying the coating. The paper can be dipped in coating or the coating can be applied by rolls or sprays. The excess may then be removed with a blade or blown away with an air jet. The goal is to make an even film of the right thickness. Uniform thickness is essential for modern high-speed printing operations.
You would not mind if a paper towel were to shrink a little or swell a little. A map used by a sea captain must never shrink or swell.
Toilet tissue must fall apart shortly after it gets wet. If it doesn't fall apart, it will plug septic systems and sewers. Paper money must hold together. Paper bags and wrapping paper should also hold together, but not necessarily as well as money. Microscopes reveal secrets of pulp fiber development. Documents, legal papers, records, and books must not fade over the years. Newspapers can fade by tomorrow for all we care.
There is no end to paper uses. Each use calls for different properties. Each property must be engineered into the paper and tested for. Just look at the variety of paper products around you. Towels, facial tissues, toilet tissues, diapers, wiping "cloths," napkins, crepe, and others make up one group. Another group is writing, printing, mimeograph, drawing, tracing, magazine, airmail, and notebook paper. Packaging materials such as wax paper, disposable fruit drink/juice containers, milk cartons, plates, cups, cans, frozen-food cartons, bags, and boxes are also a group. There are special papers such as map paper that will not shrink and photo graphic paper that cannot be made in a plant using surface water-a single particle of radioactive fallout would leave a spot on a picture. There are wallpapers; tapes of many types; smooth, glossy papers; sandpapers and emery papers; grease-proof papers; and blotters. Every use is different; every product is specially made for one use or another. The world of paper is an endless wonderland. No one can know it all. Every time you turn around someone has come up with something new. Every new product must fill a need and must be made in an economical way.
On thin paper printing is done on long rolls before the final product is cut to size and shape. On thick paper, called paperboard, sheets are first cut, then printed on flat presses. Some products are overlaid with a thin sheet of plastic, called laminating. This plastic sheet may have the printing already on it.
Much paper is formed into "folded cartons" such as cereal boxes, and into corrugated fiberboard, the three- or five-sheet structure usually called "cardboard." This product is mostly used in making shipping boxes. Printing on corrugated board is normally done after the board is formed, but sometimes the outside sheet of paper is printed before the board is made to improve printing quality.
|
to make Paper |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
![]() |
|
![]() |
|
![]() |
|
![]() |
|
![]() |
|
![]() |
The industry requires many chemists and chemical engineers to run the technical and quality control departments. In addition, many qualified technicians are needed to carry out the tests required.
Millions of gallons of water are used in papermaking. Pulp goes onto the paper machine at about 99.5 percent water, 0.5 percent fiber. The finished paper contains about 5 percent water. The water removed during processing is recycled, additional fibers are recovered, and the excess containing fines, clays, and other fillers is clarified in settling ponds. The solid material in the settling ponds is aerated to encourage biological degradation; nitrogen is added and the remaining sludge is composted and used as a clean fill, in strip mines, or on steep slopes.
Some of the chemicals used in pulping and bleaching have been found to be harmful to the environment in one way or another. Many of these chemicals can be recovered and reused. However, the acid sulfite process has, for all practical purposes, been abandoned because there was no adequate way to recover the pulping chemicals. In the other chemical pulping processes, such as kraft, spent pulping liquor is washed off the pulp. The washings are concentrated by evaporating the water. Sometimes additional useful products such as turpentine or lignin can be recovered. What remains can then be burned to help generate heat or power for the mill. Pulping chemi-cals can even be recovered from the ash. Recovery and recycling prevents many potentially hazardous chemicals from ever reaching the environment outside the mill.
An enormous amount of energy is necessary to manufacture paper. The industry has had to become more efficient in its manufacturing practices as fuel has become more expensive and concern about air pollution has become greater. Steam from the paperdrying process is recovered by heat exchangers and the heat is used in other areas of the mill. Since papermaking uses so much water, most mills are on lakeshores or along rivers. Water from these sources is used to generate some of the electric power for the mill. Wood waste from the forest, bark stripped from logs, and concentrated spent pulping liquors are all burned as fuel for the mill. The paper industry is somewhat more than 50 percent self-sufficient in energy and will continue to improve in the future.
Researchers continue to try to find better ways to make paper while causing less impact on the environment. Chemical pulping and bleaching processes are being studied that use less harsh chemicals or chemicals that are more easily recovered and reused. Better ways of treating wastewater and smokestack gases are being investigated. More energy-efficient machines and ways of generating power are being developed. Pollution control legislation, high energy costs, and concern for the natural resources upon which the industry depends are causing the forest products industry to spend much time and effort on environmental problems.